Use of detailed kinetic mechanisms for the prediction of autoignitions

Details Use of detailed kinetic mechanisms for the prediction of autoignitions Use of detailed kinetic mechanisms for the prediction of autoignitions

2007-06-14

arxiv.org/abs/0706.2067v1

Journal of Loss Prevention in the Process Industries 19 (2006) 227-232

Physics

Chemical Physics

Scientific paper

This paper describes how automatically generated detailed kinetic mechanisms are obtained for the oxidation of alkanes and how these models could lead to a better understanding of autoignition and cool flame risks at elevated conditions. Examples of prediction of the occurrence of different autoignition phenomena, such as cool flames or two-stage ignitions are presented depending on the condition of pressure, temperature and mixture composition. Three compounds are treated, a light alkane, propane, and two heavier ones, n-heptane and n-decane.

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