Transition probabilities in the HD molecule (Abgrall+, 2006)

Details Transition probabilities in the HD molecule (Abgrall+, 2006) Transition probabilities in the HD molecule (Abgrall+, 2006)

Oct 2005

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2005ycat..34450361a&link_type=abstract

VizieR On-line Data Catalog: J/A+A/445/361. Originally published in: 2006A&A...445..361A

Physics

Atomic Physics

Atomic Physics

Scientific paper

Tables 5-10 display up to the rotational quantum number J'=10, our calculated term values, total emission probabilities and total dissociation probabilities for the rovibronic levels of B, C+, B', D+, C- and D- states. (B, C+, B', D+ levels have e parity [(-1)**J'] and C- and D- states have f parity [(-1)**(J'+1)]). Only levels with the same value of J' and the same parity are coupled together by rotational or radial coupling. We have labelled the states according to the Born-Openheimer (B.O.) electronic state of greatest electronic weight factor as defined in equation (2) of the accompanying paper inside each e or f manifold.
Equation (2): {rho}(T)= integral{(fSTvJ(R))2dR}
For each rotational quantum number J' and inside each parity e or f we also indicate nu, the order of the level sorted with increasing energy term values irrespective of the B.O. state label, starting from the value of 1.
Tables 11-16 display the spontaneous emission transition probabilities and compare our calculated transition wavenumbers with experimental ones. Values have been calculated up to J'=10. The calculated transition wavenumber expressed in reciprocal centimeters, is the difference between our calculated upper rovibronic energy term and the value corresponding to the lower electronic X state. When available, we have used experimental values derived for X levels.
(12 data files).

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