Thermodynamic theory of kinetic overshoots

Details Thermodynamic theory of kinetic overshoots Thermodynamic theory of kinetic overshoots

2005-05-19

arxiv.org/abs/physics/0505135v1

Physics

Chemical Physics

IMACS2005 extended abstract

Scientific paper

Everything that is not prohibited is permissible. So, what is prohibited in the course of chemical reactions, heat transfer and other dissipative processes? Is it possible to "overshoot" the equilibrium, and if yes, then how far? Thermodynamically allowed and prohibited trajectories of processes are discussed by the example of effects of equilibrium encircling. The complete theory of thermodynamically accessible states is presented. The space of all thermodynamically admissible paths is presented by projection on the "thermodynamic tree", that is the tree of the related thermodynamic potential (entropy, free energy, free enthalpy) in the balance polyhedron. The stationary states and limit points for open systems are localized too.

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