Thermal properties of open-shell metal clusters

Physics

Scientific paper

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Scientific paper

Thermal properties of open-shell metallic nanoparticles of elements that are not magnetic in the bulk are studied within the framework of the local spin density approximation at finite temperature. For bulk ferromagnetic materials, these nanosized objects undergo a second-order critical phenomenon at a temperature that strongly depends on electron correlations and the size of the nanoparticle. The magnetic susceptibility is found to obey the Curie-Weiss law, which is in agreement with recent experimental measurements performed on mass-selected platinum clusters.

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