Thermal energy charge transfer between S2+ and H2, N2, and CO

Details Thermal energy charge transfer between S2+ and H2, N2, and CO Thermal energy charge transfer between S2+ and H2, N2, and CO

Nov 2003

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2003phrva..68e2703c&link_type=abstract

Physical Review A, vol. 68, Issue 5, id. 052703

Physics

6

Charge Transfer, Ion-Molecule, Ion-Ion, And Charge-Transfer Reactions, Optical Cooling Of Atoms, Trapping, Atomic Processes And Interactions

Scientific paper

We measured the charge transfer rate coefficients for the reactions S2++H2→products, S2++N2→products, and S2++CO→products using a radio frequency trap. S2+ ions are produced by laser ablation of a solid tungsten disulfide target. We derive the rate coefficient of the reaction from the decay rate of the stored ions in the trap. The rate coefficients for the above three reactions are 1.58(0.13)×10-9 cm3 s-1 at Tequiv=1077 K, and 1.67(0.12)×10-9 and 1.78(0.13)×10-9 cm3 s-1 at Tequiv=6462 K.

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