Physics – History and Philosophy of Physics
Scientific paper
2010-02-16
Physics
History and Philosophy of Physics
Scientific paper
This paper looks at the theory underlying the science of materials from the perspectives of physics, the history of science, and the philosophy of science. We are particularly concerned with the development of understanding of the thermodynamic phases of matter. The question is how can matter, ordinary matter, support a diversity of forms. We see this diversity each time we observe ice in contact with liquid water or see water vapor (steam) rise from a pot of heated water. The nature of the phases is brought into the sharpest focus in phase transitions: abrupt changes from one phase to another and hence changes from one behavior to another. This article starts with the development of mean field theory as a basis for a partial understanding of phase transition phenomena. It then goes on to the limitations of mean field theory and the development of very different supplementary understanding through the renormalization group concept. Throughout, the behavior at the phase transition is illuminated by an "extended singularity theorem", which says that a sharp phase transition only occurs in the presence of some sort of infinity in the statistical system. The usual infinity is in the system size. Apparently this result caused some confusion at a 1937 meeting celebrating van der Waals, since mean field theory does not respect this theorem. In contrast, renormalization theories can make use of the theorem. This possibility, in fact, accounts for some of the strengths of renormalization methods in dealing with phase transitions. The paper outlines the different ways phase transition phenomena reflect the effects of this theorem.
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