Theoretical study of the absorption spectra of the lithium dimer

Details Theoretical study of the absorption spectra of the lithium dimer Theoretical study of the absorption spectra of the lithium dimer

1999-05-27

arxiv.org/abs/physics/9905054v1

Phys. Rev. A, 60 (1999) 2002

Physics

Atomic Physics

20 pages, revtex, epsf, 6 figs

Scientific paper

10.1103/PhysRevA.60.2002

For the lithium dimer we calculate cross sections for absorption of radiation from the vibrational-rotational levels of the ground X [singlet Sigma g +] electronic state to the vibrational levels and continua of the excited A [singlet Sigma u +] and B [singlet Pi u] electronic states. Theoretical and experimental data are used to characterize the molecular properties taking advantage of knowledge recently obtained from photoassociation spectroscopy and ultra-cold atom collision studies. The quantum-mechanical calculations are carried out for temperatures in the range from 1000 to 2000 K and are compared with previous calculations and measurements.

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