Theoretical studies of possible processes for the interstellar production of phosphorus compounds: the reaction of P+ with C3H2.

Details Theoretical studies of possible processes for the interstellar production of phosphorus compounds: the reaction of P+ with C3H2. Theoretical studies of possible processes for the interstellar production of phosphorus compounds: the reaction of P+ with C3H2.

Aug 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jphrh.10014643d&link_type=abstract

Journal of Physical Chemistry, Vol. 100, No. 35, p. 14643 - 14650

Physics

Molecular Processes: Phosphorus, Molecular Processes: Interstellar Molecules

Scientific paper

An ab initio study of the (PC3H)+ and (PC3H2)+ species was carried out. Since the ionization potential of C-C3H2 is lower than that of phosphorus, the reaction in the interstellar medium is more likely to be initiated by P+c-C3H2+. In that case, only production of a four-membered ring PC3H+ species should be feasible. The reactions of P with c-C3H2+ and of P+ with 1-C3H2 are feasible in the interstellar medium and consequently possible sources of precursors of C3P in space.

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