Theoretical determination of the spectroscopic constants of CaH+

Details Theoretical determination of the spectroscopic constants of CaH+ Theoretical determination of the spectroscopic constants of CaH+

Sep 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993phrva..48.2461c&link_type=abstract

Physical Review A (Atomic, Molecular, and Optical Physics), Volume 48, Issue 3, September 1993, pp.2461-2463

Physics

6

Radio-Frequency And Microwave Spectra, Radio, Microwave

Scientific paper

Fourth-order many-body perturbation-theory calculations of the spectroscopic constants of CaH+ are presented as an attempt to help identify possible astronomical or laboratory observations. The results for the rotational and vibrational constants are, respectively, 4.61 and 1511 cm-1. Similar calculations are made on MgH+, where comparison with experimental values shows excellent agreement, indicating reliable results for CaH+

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