The ultraviolet absorption spectrum of hot carbon dioxide.

Details The ultraviolet absorption spectrum of hot carbon dioxide. The ultraviolet absorption spectrum of hot carbon dioxide.

Oct 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997cpl...277..356j&link_type=abstract

Chem. Phys. Lett., Vol. 277, No. 4, p. 356 - 360

Physics

6

Uv Spectra: Carbon Dioxide, Uv Spectra: Solar Spectrum

Scientific paper

The vacuum ultraviolet absorption spectrum of CO2 shifts significantly to longer wavelengths with increasing temperature. The authors have measured this temperature dependence and present absorption cross sections for 230 to 355 nm at temperatures from 1523 to 2273K. At 2273K this red shift extends the absorption above 300 nm and well into the blue end of the solar spectrum. In CO2 the thermal shift is enhanced because of the relative position and shapes of the excited and ground state potential curves.

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