Physics
Scientific paper
Oct 1981
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1981gecoa..45.1743w&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 45, Issue 10, pp.1743-1750
Physics
2
Scientific paper
Freshwater humic substances from Lake Celyn, Gwynedd, N. Wales have been investigated by 13 C-NMR spectroscopy. Carboxyl, aromatic, o -alkyl and alkyl resonances can be recognised. Varying pulse delay from 0.43 s to 2.5 sec has little effect on the magnitude of the signal ascribed to aromatic carbon, but there is a small nuclear Overhauser effect (1.45 at a pulse delay of 0.8 sec). The results show-that 24% of the Lake Celyn humic acid carbon is carboxyl and 40% is aromatic. The high proportion of aromatic carbon suggests the Lake Celyn humic acid is largely formed from terrestrial humic substances from the surrounding peaty watershed.
Barron P. F.
Gillam A. H.
Wilson Margaret A.
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