The Second Spectrum of Silicon

Details The Second Spectrum of Silicon The Second Spectrum of Silicon

Apr 1961

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1961rspsa.261..153s&link_type=abstract

Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 261, Issue 1305, pp. 153-174

Physics

52

Scientific paper

New observations of the spectrum SiII from λ 700 to λ 9500 are described, 300 lines being listed in addition to those previously assigned to this spectrum. The analysis includes details of the perturbations of the 3s^2nx^2X series up to x=g. Structures of type 3s3p(^3P)nx up to x=f have been identified and many peculiarities found. A large proportion of the levels show auto-ionization effects, even up to a term at 25000 cm-1 above ionization. The same term also shows an anomalous degree of excitation in the hollow cathode for two levels which cannot auto-ionize.

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