Physics
Scientific paper
Nov 1994
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994georl..21.2543s&link_type=abstract
Geophysical Research Letters (ISSN 0094-8276), vol. 21, no. 23, p. 2543-2546
Physics
25
Air Pollution, Air Sampling, Atmospheric Chemistry, Atmospheric Effects, Chlorine Oxides, Concentration (Composition), Nitrogen Oxides, Ozone, Radicals, Stratosphere, Abundance, Chemical Reactions, Photochemical Reactions, Photolysis, Pollution Monitoring
Scientific paper
The respose of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of (ClO), (NO), (NO2) and (O3) in the midlatitude lower stratosphere. This analysis demonstrates that (ClO) is inversely correlated with (NO2), consistent with formation and photolysis of (ClONO2). A factor of ten range in the concentration if NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cu cm), with a comparable range in the ratio of (ClO) to total available inorganic chlorine (1% less than or equal to (ClO)/(Cl(sub y)) less than or equal to 5%. This analysis leads to an estimate of (ClONO2)/(Cl(sub y)) = 0.12 (x/2), in the mid-latitude, lower-stratospheric air masses sampled.
Anderson James G.
Avallone Linnea M.
Cohen Ronald C.
Judah D. M.
Kohn D. W.
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