The Primary Process in the Photolysis of Hexafluoroacetone Vapour. I. Photodecomposition Studies

Details The Primary Process in the Photolysis of Hexafluoroacetone Vapour. I. Photodecomposition Studies The Primary Process in the Photolysis of Hexafluoroacetone Vapour. I. Photodecomposition Studies

Sep 1968

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1968rspsa.306..503w&link_type=abstract

Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 306, Issue 1487, pp. 503-510

Physics

3

Scientific paper

An investigation has been made of the effect of ketone concentration, of temperature, of the wavelength of the exciting light and of the concentration of an inert addend on the quantum yield for the decomposition of hexafluoroacetone vapour. All data were obtained in an apparatus free of mercury vapour. General trends shown by the data are those predicted by the mechanism offered. In particular the value of the quantum yield extrapolated to infinite concentration of ketone depends only on the temperature and not on the wavelength of excitation. The data will be discussed further in part V.

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