The pressure medium as a solid-state oxygen buffer

Physics

Scientific paper

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Mineralogy And Petrology: Experimental Mineralogy And Petrology, Mineralogy And Petrology: Instruments And Techniques, Mineral Physics: Instruments And Techniques

Scientific paper

We present a simple method to buffer oxygen fugacity at high pressures and high temperatures where the traditional 'double capsule' method is inappropriate. The pressure medium is doped with a metal which partially reacts with the free oxygen in the pore spaces of the cell. The resultant finely intergrown metal-metal oxide assemblage buffers the oxygen fugacity in the sample as long as the capsule and furnace materials are oxygen permeable.

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