The pressure dependence of the Herzberg photoabsorption continuum of oxygen

Details The pressure dependence of the Herzberg photoabsorption continuum of oxygen The pressure dependence of the Herzberg photoabsorption continuum of oxygen

Aug 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jqsrt..38..113b&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 38, Aug. 1987, p. 113-120. Research supported

Computer Science

Numerical Analysis

18

Forbidden Transitions, Herzberg Bands, Oxygen Spectra, Photoabsorption, Pressure Dependence, Temperature Dependence, Absorption Spectra, Cross Sections, Diatomic Molecules, Numerical Analysis

Scientific paper

The origin of pressure dependence in the dipole forbidden Herzberg continuum of oxygen is discussed in terms of the formation of oxygen dimers and the collision of free molecules. The small temperature dependence of the pressure coefficient indicates that the collisions of free molecules have the dominant influence. Consideration of the selection rules applying to the Herzberg systems and the strengths of the associated band systems leads to the conclusion that the pressure dependence results from enforced dipole transitions in the Herzberg III A-prime 3Delta(u) - X 3Sigma(-g) system.

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