The possible effects of translationally excited nitrogen atoms on lower thermospheric odd nitrogen

Physics

Scientific paper

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Atmospheric Chemistry, Hot Atoms, Nitric Oxide, Nitrogen Atoms, Photochemical Reactions, Thermosphere, Chemical Equilibrium, Photolysis

Scientific paper

In the quiet lower thermosphere, photolysis of N2 produces translationally excited N(4S) and N(2D) atoms. A fraction of these N(4S) atoms may react rapidly with O2 while still translationally hot. This results in substantially larger calculated NO densities than those obtained if translational excitation is not considered. The sensitivity of the calculated NO density in the lower thermosphere to this process is examined.

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