The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes

Details The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confemf09r&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Physics

Dynamics

Scientific paper

The incorporation of tolylethynylcarboxylate and anthrylethynylcarboxylate ligands into quadruply bonded dimetal complexes has been achieved. Their photophysical properties have been investigated by fs-transient absorbance, ns-transient absorbance, visible and near-IR emission. These dimetal complexes, where M = molybdenum, exhibit two excited states: one short-lived (fs) and one long-lived (μs). The higher energy emission associated with the short lived excited state has been assigned as the ^{1}MLCT based on the small stokes shift and DFT-calculations. DFT-calculations of the lowest energy triplet state along with the vibronic features of the lowest energy emission have allowed the long lived excited state to be assigned as metal based in character.

Affiliated with

Also associated with

No associations

Rating

The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and The Photophysical Properties of Quadruply Bonded M_2 Arylethynylcarboxylate Complexes will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1641352