Physics – Chemical Physics
Scientific paper
2005-02-25
Physics
Chemical Physics
10 pages and 1 figure
Scientific paper
Ornstein and his coauthors, who constructed a dynamical theory of Brownian motion, taking the equation $mdv/dt =-\zeta v+X$ as their starting point, usually named the equation after Einstein alone or after both Einstein and Langevin; furthermore, Ornstein, who was the first to extract from this equation the correct expression for $\bar{\Delta^2}$, the mean-squared distance covered by a Brownian particle, credited de Haas-Lorentz, rather than Langevin, for finding the stationary limit of $\bar{\Delta^2}$. A glance at Einstein's 1907 paper, titled ``Theoretical remarks on Brownian motion'', should suffice to convince one that it is not unfair to attribute the {\it conception} of the above equation, now universally known as the Langevin equation, to Einstein. Langevin's avowed aim in his 1908 article was to recover, through a route that was `infinitely more simple', Einstein's 1905 expression for the diffusion coefficient, but a careful reading of Langevin's paper shows that--depending on how one interprets his description of the statistical behavior of the random force $X$ appearing in the above equation--his analysis is at best incomplete, and at worst a mere tautology. Since textbook accounts are based on the interpretation that renders the proof fallacious, alternative derivations, which are adaptations of those given by de Haas-Lorentz and Ornstein, are presented here. Some neglected aspects of the contents of Ornstein's early papers on Brownian motion are also brought to light.
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