The NO-NO2 system at laboratory surfaces

Physics

Scientific paper

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Charged Particles, Desorption, Infrared Radiation, Luminescence, Neutral Particles, Nitrous Oxides, Radiative Lifetime, Space Shuttle Orbiters, Spatial Distribution, Spectral Energy Distribution, Surface Reactions, Velocity, Wall Temperature, Fluorescence, Laser Outputs, Polycrystals, Remote Control, Silicon Dioxide, Tiles, Transition Metals

Scientific paper

Experiments on formation and excitation of NO2 and NO molecules at (and near) laboratory surfaces of varying degrees of characterization are reviewed. On some transition metals NO is desorbed in the B2 pi state, from which it radiates the familiar beta (B yields x) bands. In contrast while an ONO intermediate is inferred from isotope interchange measurements on platinum, neither ground state nor excited NO2 has been found to be desorbed under the relatively limited number of laboratory conditions so far investigated.

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