Physics – General Physics
Scientific paper
1999-09-24
Physics
General Physics
61 pages with figures in 41gif files
Scientific paper
The MCAS Way extends the MCAS concept of atomic orbitals to molecular bonding. There are many examples given for each bonding type. Part I: The MCAS atomic orbital concept. There are no spherical orbitals and spin pairing does not occur through spin reversal. Quantum numbers do not validate coexistence in identical space. Part II: Single bonds. There are no sigma-bonds wherein two electrons occupy identical space on a line between nuclei; only off-axis (Xi) bonding. Covalent bonding is purely electrostatic; just like ionic bonding. Part III: Triple bonds. There are no Pi-bonds in a triple bond. Part IV: Simple double bonds. There are no sigma bonds; only Pi| and Pi_ bonds. Part V: Multiple bonds. The traditional Pi-cloud is only a group of reciprocating, vertically pumping, electron pistons. Electrons conjugate by flowing around nuclei in the nuclear plane. Atoms adopt a twelve-lobed (T12) orbital arrangement for multiple bonding. Aromaticity is defined by 2(2n+1), not (4n+2). Part VI: Miscellaneous compounds. Isoelectronic XO3, phosphorous and its oxides, and boranes.
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