The location of Fe3+ ions in forsterite (Mg2SiO4)

Details The location of Fe3+ ions in forsterite (Mg2SiO4) The location of Fe3+ ions in forsterite (Mg2SiO4)

Jan 1974

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974e%26psl..21..201z&link_type=abstract

Earth and Planetary Science Letters, Volume 21, Issue 2, p. 201-208.

Physics

1

Scientific paper

The electron spin resonance spectrum of Fe3+ in a single crystal of forsterite was studied. Two distinct patterns of about equal intensities were observed which are due to Fe3+ at two distinct positions with 4a (M1) and 4c (M2 or Si) symmetry of Pbnm. The assignment of the 4c pattern to Fe3+ ions at the Si position cannot be excluded by symmetry but it is unlikely. The Hamiltonian parameters A and E/D are consistent with the conclusion that Fe3+ in this crystal is disordered over two distinct octahedral positions.

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