The heat of formation of CN radicals and radiative lifetimes of the A1Σ- state of C2N2.

Details The heat of formation of CN radicals and radiative lifetimes of the A1Σ- state of C2N2. The heat of formation of CN radicals and radiative lifetimes of the A1Σ- state of C2N2.

May 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990nascp3077..221b&link_type=abstract

"Laboratory

Physics

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Radiative lifetimes have been measured for the stable vibrational levels of the A1Σ- electronic state of C2N2. They range from 1.3 μs for the 401 level to 0.66 μs for the 101401 level and in general decrease with increasing vibrational excitation. Self-quenching rate constants range from gas kinetic to ten times that. Foreign gas quenching rates are slower. Observation of emission from the 101401 level sets a lower limit for the heat of formation of CN of 439.11 kJ mol-1.

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