The first hexad (040), (120), (021), (200), (101), (002) of H2(O-18) - Experimental energy levels and line intensities

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Infrared Absorption, Molecular Energy Levels, Molecular Rotation, Oxygen 18, Vibrational Spectra, Water Vapor, Absorption Spectra, Fourier Transformation

Scientific paper

The spectrum of O-18 enriched water vapor has been recorded between 5900 and 8000/cm, with the aid of a Fourier-transform spectrometer. Its analysis allowed the determination of 437 accurate rotational levels belonging to the hexad of interacting states (040), (120), (021), (200), (101), (002) of H2(O-18). Among these vibrational states, the (040), (120), and (002) ones had never been observed before. Moreover, 726 line intensities belonging to the 4nu2, nu1 + 2nu2, 2nu2 + nu3, 2nu1, nu1 + nu3, and 2nu3 bands have been measured with an uncertainty of 6 percent.

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