Physics
Scientific paper
Aug 1969
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1969gecoa..33..987t&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 33, Issue 8, pp.987-996
Physics
78
Scientific paper
Calcite, aragonite and magnesian calcite were slowly precipitated from aqueous bicarbonate solutions, and oxygen isotope fractionation factors between the precipitate and water were measured. For calcite-water at 25°C and 0°C, 1000 ln = 28.1 and 33.7, respectively, both values in excellent agreement with the Urey-Epstein paleotemperature scale. Aragonitewater at 25°C gave 28.7, implying a small but significant fractionation between aragonite and calcite. O 18 also concentrates in magnesian calcite, relative to pure calcite precipitated under the same conditions, by 0.06%. for each mole-percent MgCO 3 in calcite.
Clayton Robert N.
Mayeda Toshiko K.
Tarutani Toshikazu
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