The E.P.R. Spectrum of Vibrationally Excited Hydroxyl Radicals

Details The E.P.R. Spectrum of Vibrationally Excited Hydroxyl Radicals The E.P.R. Spectrum of Vibrationally Excited Hydroxyl Radicals

Jul 1971

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1971rspsa.323..541c&link_type=abstract

Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 323, Issue 1555, pp. 541-554

Physics

7

Scientific paper

The e.p.r. spectrum of vibrationally excited hydroxyl radicals in levels v = 1, 2, 3 and 4 of the 2Pi 3/2 ground state has been observed in the reaction between hydrogen atoms and ozone in the gas phase. Although the variation of Λ -doubling with vibrational energy superficially agrees well with the 'pure precession' model of Van Vleck, there is clear evidence that the matrix element < Pi|Ly|Σ > decreases considerably with increasing internuclear distance. The form of the decrease in the hyperfine coupling constants with increasing vibrational energy agrees well with that deduced from Kayama's theoretical calculations.

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