The discovery of two new infrared electronic transitions of C2: B1Δg-A1Πu and B'1Σg+-A1Πu

Details The discovery of two new infrared electronic transitions of C2: B1Δg-A1Πu and B'1Σg+-A1Πu The discovery of two new infrared electronic transitions of C2: B1Δg-A1Πu and B'1Σg+-A1Πu

Oct 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988jmosp.131..261d&link_type=abstract

Journal of Molecular Spectroscopy, Volume 131, Issue 2, p. 261-271.

Physics

38

Scientific paper

Two new infrared electronic transitions of C2, B1Δg-A1Πu and B'1Σg+-A1Πu, were observed by Fourier transform emission spectroscopy of hydrocarbon discharges. A set of spectroscopic constants were derived for each vibrational level and then reduced to equilibrium constants, including
Te (cm-1)ωe (cm-1)re (Å)
B1Δg12 082.3360(40)1407.4653(13)1.38548
B'1Σg+15 409.1390(39)1424.11891.37735 RKR curves and Franck-Condon factors were calculated from the equilibrium constants.
Alfred P. Sloan Fellow; Camille and Henry Dreyfus Teacher-Scholar.

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