The Ca I Absorption Spectrum in the Vacuum Ultraviolet: Excitation of the 3p-Subshell

Details The Ca I Absorption Spectrum in the Vacuum Ultraviolet: Excitation of the 3p-Subshell The Ca I Absorption Spectrum in the Vacuum Ultraviolet: Excitation of the 3p-Subshell

Oct 1977

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1977rspsa.357...77m&link_type=abstract

Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 357, Issue 1688, pp. 77-102

Physics

63

Scientific paper

The Ca I absorption spectrum between 300 and 800 angstrom (41-10 eV) has been photographed revealing at least 125 new lines. All the stronger lines are identified by comparison with Hartree-Fock calculations. In addition to single electron excitation of the 3p-subshell there is clear evidence of a simultaneous excitation of the 4s valence subshell and a 3p-subshell electron. The more important processes of multi-electron excitation are indicated. The general case of 3p --> 3d excitation in elements Z = 18 to 28 is discussed and is illustrated by plots of the effective central potentials for 3d wavefunctions derived from the Hartree-Fock results.

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