The atmospheric degradation of 1-bromopropane (CH3CH2CH2Br): The photochemistry of bromoacetone

Details The atmospheric degradation of 1-bromopropane (CH3CH2CH2Br): The photochemistry of bromoacetone The atmospheric degradation of 1-bromopropane (CH3CH2CH2Br): The photochemistry of bromoacetone

Sep 2002

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2002georl..29q...3b&link_type=abstract

Geophysical Research Letters, Volume 29, Issue 17, pp. 3-1, CiteID 1822, DOI 10.1029/2002GL014712

Physics

6

Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Troposphere-Composition And Chemistry

Scientific paper

The atmospheric degradation of 1-bromopropane and its degradation products are examined with respect to their ability to deplete stratospheric ozone. It is shown that the OH initiated oxidation of 1-bromopropane does not lead to long lived bromine containing species. Laboratory measurements of the UV absorption cross sections and photodissociation quantum yields of chloroacetone and bromoacetone are presented. The atmospheric photolysis lifetime of bromoacetone at mid-latitudes is determined to be on the order of hours.

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