The action of borontrifluoride-methanol on isoprenoid alcohols

Details The action of borontrifluoride-methanol on isoprenoid alcohols The action of borontrifluoride-methanol on isoprenoid alcohols

Oct 1976

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1976gecoa..40.1289i&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 40, Issue 10, pp.1289-1290

Physics

Scientific paper

BF 3 -methanol, commonly used for esterification of carboxylic acids, also reacts with some alcohols to give a mixture of methyl ethers. The reaction appears to be limited to allylic alcohols with an alkyl branch at the allylic alcohol group (e.g. phytol). Neither straight chain alcohols nor saturated isoprenoid alcohols react under the prescribed reaction conditions.

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