The absence of 6-fold coordinated Al in jadeite melt near the jadeite liquidus

Physics

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Scientific paper

A 27 Al MAS NMR study indicates that Jadeite and Jadeite glass produced on the liquidus at 1390° ± 25° C and 35 kbars had Al in two different coordinations. In the solid phase Al was 6-fold and in the glass it was 4-fold. If the glass is taken as a good model for the liquid phase, then the common assumption that the structure of precipitating crystals reflects the structure of the melt must not be automatically accepted.

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