The A2Πi-X2Σ+ system of CP: Observation of new bands

Details The A2Πi-X2Σ+ system of CP: Observation of new bands The A2Πi-X2Σ+ system of CP: Observation of new bands

Mar 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jmosp.152...89r&link_type=abstract

Journal of Molecular Spectroscopy, Volume 152, Issue 1, p. 89-100.

Physics

14

Scientific paper

Infrared emission spectra of the A2Πi-X2Σ+ system of CP have been observed at high resolution using a Fourier transform infrared spectrometer. The rotational structure of seven new bands involving vibrational levels up to v = 4 of both electronic states has been analyzed and equilibrium molecular constants have been determined. For the X2Σ+ state ωe = 1239.77924(8) cm-1 and re = 1.5619780(2) Å were derived, while for the A2Πi state the corresponding values are ωe = 1062.47140(98) cm-1 and re = 1.654420(6) Å.
Also: Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.

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