The A 3Sigma(-)-X 3Pi transition of the SiC radical

Details The A 3Sigma(-)-X 3Pi transition of the SiC radical The A 3Sigma(-)-X 3Pi transition of the SiC radical

Dec 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989jchph..91.7384b&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 91, Dec. 15, 1989, p. 7384-7386. Research supported by the Petroleum Research

Physics

Chemical Physics

28

Electron Transitions, Free Radicals, Silicon Carbides, Spectral Bands, Electron States, Emission Spectra, Fourier Transformation, Ground State, Molecular Spectra

Scientific paper

Observations have been obtained in emission near 4500/cm of the 0-0 band in SiC's A 3Sigma(-)-X 3Pi system. Internuclear separations are ascertained to be 1.81356 A for the A 3Sigma(-) state and 1.72187 A for the X 3Pi state. The ground molecular constants obtained and presented in tabular form are in good agreement with the values previously reported by Cernicharo et al. (1989), although it is expected that the present X 3Pi constants should be slightly superior.

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