The 1Πu<-- X 1Σg+ electronic spectrum of C5 in the gas phase

Details The 1Πu<-- X 1Σg+ electronic spectrum of C5 in the gas phase The 1Πu<-- X 1Σg+ electronic spectrum of C5 in the gas phase

Oct 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999jchph.111.6161m&link_type=abstract

Journal of Chemical Physics, Volume 111, Issue 14, pp. 6161-6163 (1999).

Physics

Chemical Physics

14

Visible Spectra, Vibronic, Rovibronic, And Rotation-Electron-Spin Interactions, Line And Band Widths, Shapes, And Shifts, Molecular And Chemical Processes And Interactions, Atomic And Molecular Data, Spectra, And Spectral Parameters

Scientific paper

The origin and three vibronic bands of the 1Πu<--X 1Σg+ electronic transition of linear C5 have been observed in the gas phase. The carbon chain is produced in a slit nozzle employing both discharge and ablation techniques. Cavity ring down spectroscopy is used to measure the electronic transition. The origin band is found at 510.94(1) nm, shifted 29 cm-1 to the red of the value in a neon matrix. Intramolecular processes lead to broadening and irregularities in the rotational structure. The relation to astronomical observations is discussed.

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