Temperature effect on the ultraviolet absorption of CFCl3, CF2Cl2 and N2O

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Absorption Cross Sections, Atmospheric Temperature, Chlorocarbons, Fluorocarbons, Nitrous Oxides, Photodissociation, Beer Law, Chlorofluorocarbons, Temperature Effects

Scientific paper

The absorption cross-section of chlorofluorocarbons CFCl3, and CF2Cl2 and of nitrous oxide N2O have been measured with long absorption paths in the spectral region above 200 nm for temperatures ranging from 220 to 296 K. The spectral range for accurate measurements has thus been extended toward longer wavelengths where the cross-section values are low. The results are compared with previous determinations and photodissociation coefficients are evaluated in consideration of the most recent data for the atmospheric transmittance.

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