Temperature dependence of the ozone absorption spectrum over the wavelength range 410 to 760 nm

Details Temperature dependence of the ozone absorption spectrum over the wavelength range 410 to 760 nm Temperature dependence of the ozone absorption spectrum over the wavelength range 410 to 760 nm

Apr 1994

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994georl..21..581b&link_type=abstract

Geophysical Research Letters, Volume 21, Issue 7, p. 581-584

Physics

40

Atmospheric Composition And Structure: Transmission And Scattering Of Radiation, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Atmospheric Composition And Structure: Troposphere-Composition And Chemistry

Scientific paper

The ozone, O3, absorption cross sections between 410 and 760 nm, the Chappuis band, were measured at 220, 240, 260, and 280 K relative to that at room temperature using a diode array spectrometer. The measured cross sections varied very slightly, <1%, with decreasing temperature between 550 and 660 nm, near the peak of the Chappuis band. At wavelengths away from the peak, the absorption cross sections decrease with decreasing temperature; e.g., ~40% at 420 nm between 298 and 220 K. These results are compared with previous measurements and the impact on atmospheric measurements are discussed.

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