Physics
Scientific paper
Apr 1994
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994georl..21..585b&link_type=abstract
Geophysical Research Letters, Volume 21, Issue 7, p. 585-588
Physics
20
Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Atmospheric Composition And Structure: Troposphere-Composition And Chemistry
Scientific paper
The temperature dependence of the ClONO2 absorption spectrum has been measured between 220 and 298 K and between 195 and 430 nm using a diode array spectrometer. The absorption cross sections were determined using both: (1) absolute pressure measurements at 296 K and (2) measurements at various temperatures relative to 296 K using a dual absorption cell arrangement. The temperature dependence of the ClONO2 absorption spectrum shows very broad structure. The amplitude of the temperature dependence relative to that at 296 K is weak at short wavelengths, <2% at 215 nm and 220 K, but significant at the wavelengths important in the stratosphere ~30% at 325 nm and 220 K. Our ClONO2 absorption cross section data are in good general agreement with the previous measurements of Molina and Molina [1979].
Burkholder James B.
Ravishankara A. R.
Talukdar Ranajit K.
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