Synthesis and crystal-chemical characterization of MgSiO3 perovskite

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Scientific paper

The orthorhombic MgSiO3 perovskite has been synthesized with the aid of a double-stage split-sphere-type high-pressure apparatus at about 280 kbar and 1000°C. The unit cell dimensions are: a = 4.7754(3) Å, b = 4.9292(4) Å and c = 6.8969(5) Å with the probable space group Pbnm. Calculated density is 4.108 g cm-3. Crystal structure determination has been carried out by means of both the geometrical simulation (DLS) technique and the ordinary powder X-ray analysis. The results indicate that the MgSiO3 perovskite is closer to the ideal perovskite than ScAlO3 perovskite.

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