Symmetry Adaptation in Two-Photon Spectroscopy

Details Symmetry Adaptation in Two-Photon Spectroscopy Symmetry Adaptation in Two-Photon Spectroscopy

1998-11-18

arxiv.org/abs/physics/9811032v1

Published in "Excited States of Transition Elements", Eds. W. Strek, W. Ryba-Romanowski, J. Legendziewicz, and B. Jezowska-Trz

Physics

Atomic and Molecular Clusters

11 pages, Tex file. Invited lecture at the "Second International School on Excited States of Transition Elements", Wroclaw-Kar

Scientific paper

Symmetry adaptation techniques are applied to the determination of the intensity of two-photon transitions for transition ions in finite symmetry environments. We treat the case of intra-configurational transitions with some details and briefly report some results on inter-configurational transitions. In particular, for intra-configurational transitions, we describe a model which takes into account the following ingredients: symmetry, second- plus third- order mechanisms, S-, L- and J-mixings.

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