Submillimeter spectroscopy on OH(+) - The rotational transition at 1 THz

Details Submillimeter spectroscopy on OH(+) - The rotational transition at 1 THz Submillimeter spectroscopy on OH(+) - The rotational transition at 1 THz

Apr 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985jchph..82.3868b&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 82, April 15, 1985, p. 3868, 3869.

Physics

Chemical Physics

20

Hydroxyl Radicals, Hyperfine Structure, Infrared Spectroscopy, Molecular Rotation, Spin Dynamics, Submillimeter Waves, Comet Tails, Ground State, Hamiltonian Functions, Interstellar Matter, Magnetic Dipoles, Optical Emission Spectroscopy

Scientific paper

A report is presented of the first observation and complete analysis of the spin multiplet and hyperfine structure of the lowest rotational transition (N = 0 to 1) in the X 3 Sigma -, v = 0 ground state of the hydroxyl cation OH(+). The discussed study provides molecular constants for the ground state and yields accurate frequencies for the lowest transitions which may facilitate detection of OH(+) in interstellar clouds. The observed spectrum has been fitted to an appropriate Hamiltonian describing the rotational and fine structure and the magnetic hyperfine structure of a 3 Sigma state.

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