Physics
Scientific paper
Jan 2007
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2007gecoa..71..145b&link_type=abstract
Geochimica et Cosmochimica Acta, Volume 71, Issue 1, p. 145-154.
Physics
1
Scientific paper
Structural incorporation of the actinide curium in the octahedral layer of the trioctahedral Mg-rich smectite hectorite was studied using time-resolved laser fluorescence spectroscopy. Organo-hectorite nanoparticles were synthesized at 90 °C in the presence of Cm(III). Within 120 h, hectorite particles were formed. Time-resolved laser fluorescence spectroscopy was used to identify Cm(III) species during various synthesis steps and to characterize the structural incorporation mechanism. The formation of a Cm-containing Mg hydroxide precursor and the reaction with aqueous silica in a pH range of 9 10 to form TOT layers were identified to be key steps for trivalent actinide incorporation in hectorite via coprecipitation.
Bosbach Dirk
Brandt Heike
Fanghänel Thomas
Panak Petra J.
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