Structural and electrical relations of monosulphide solid solution in the Fe-Ni-S system at high pressures and temperatures

Physics

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Scientific paper

Monosulphide solid solution in the Fe-Ni-S system was synthesised at high pressure and temperature, and its electrical conductivity measured at several pressures and as a function of temperature. The results show a non-classic transition from semiconducting to metallic behaviour in the samples under pressure. The influence of pressure as a function of composition shows the tendency to a relative shift of the properties towards the Ni-rich end. Correspondingly one also can consider the influence of temperature as a shift towards Fe-rich compositions.

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