Physics
Scientific paper
Jun 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..conferh09c&link_type=abstract
"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec
Physics
Microwave
Scientific paper
The pure rotational spectra of the ground states of silacyclobutane (SCB) and silacyclopentane (SCP) were measured in a supersonic jet in the 6-24 GHz range using Fourier transform microwave spectroscopy and the chirped-pulse variant of this technique. Heavy atom isotopic substitution for the silicon and each of the carbon atoms within the rings enabled the accurate determination of the RS and R0 structural parameters of the ring backbones of both SCB and SCP. For SCB, splitting due to ring inversion in the ground state has been observed and analyzed.
Chen Ziqiu
Dijk Cody Van
Wijngaarden Jennifer Van
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