Stark-modulation spectroscopy of the B(1)$[^3Π]$ state of PbO

Details Stark-modulation spectroscopy of the B(1)$[^3Π]$ state of PbO Stark-modulation spectroscopy of the B(1)$[^3Π]$ state of PbO

2005-09-21

arxiv.org/abs/physics/0509176v2

Phys. Rev. A 72 (2005) 064501

Physics

Atomic Physics

REVTex 4, 4 pages, 2 figures, updated author information, removed typos

Scientific paper

10.1103/PhysRevA.72.064501

We report detailed spectroscopic measurements of the X(0)$[^3\Sigma^+]$(v=0) to B(1)$[^3\Pi]$ (v=5) transition in PbO. Using a Stark-modulated laser absorption technique, we have measured the hyperfine constant of $^{207}$PbO in the B(1) state, as well as B(1)(v=5) rotational constant, X-B isotope shifts, etc. The hyperfine structure of the B(1) state is of interest as a benchmark for calculations of PbO electronic structure, related to experiments to search for the electric dipole moment of the electron.

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