Spring measurements of tropospheric bromine at Barrow, Alaska

Physics

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Atmospheric Composition, Bromine, Spring (Season), Troposphere, Alaska, Chlorine, Inorganic Compounds, Marine Environments, Organic Compounds, Photochemical Reactions

Scientific paper

The partitioning of bromine in the lower troposphere between particulate, inorganic gaseous, and organic gaseous phases was measured during the arctic spring. Rapid photochemical production of particulate Br from organic gaseous Br was indicated by (1) an inverse correlation between particulate bromide and organic gaseous bromine, (2) a diurnal cycle in the ratio of these two phases, and (3) a diurnal cycle in the ratio of organic gaseous Br to Cl. Organic gaseous Br and Cl were correlated indicating a common, possibly marine, source.

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