Spin Hamiltonian Parameters of Cr3+ In LiNbO3

Physics

Scientific paper

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Crystal And Ligand Fields, Impurity And Defect Levels, Crystal-Field Theory And Spin Hamiltonians

Scientific paper

The spin- Hamiltonian parameters D, g factors and first excited state
splitting δ(2E) for Cr3+ ion in γ-LiNbO3 crystal are
calculated. The method is based on the two-spin-orbit-coupling parameter
model, in a cluster approach using Macfarlane's high order perturbation
formulae. The results are compared with experimental data.

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