Spectral line shapes for atmospheric work: Problems and solutions

Physics

Scientific paper

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Spectral Absorption By Atmospheric Gases

Scientific paper

We discuss the application of spectral line shapes to atmospheric physics. Two problems are identified, one of which requires detailed knowledge of spectral profiles over a limited region of the infrared. A simple master transport relaxation equation is proposed for the off-diagonal elements of the density matrix, the solution of which leads to a band profile. Exemplary solutions are then given, wherein a matrix technique is used to treat speed dependent broadening, shifting and line mixing. With reasonable computer power, detailed spectra may be constructed over regions containing tens if not hundreds of lines.

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