Solving the Puzzle of Tetratomic, 23-VALENCE-ELECTRON Molecules

Details Solving the Puzzle of Tetratomic, 23-VALENCE-ELECTRON Molecules Solving the Puzzle of Tetratomic, 23-VALENCE-ELECTRON Molecules

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confewj03j&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Radicals And Ions

Scientific paper

Because of extensive electron correlation, the ground-state structures, infrared spectra, and chemical bonding properties of a number of tetratomic molecules which possess 23 valence electrons are anomalous. Approaches which have recently been helpful in understanding this phenomenon include ab initio calculations and spectroscopic observations of these species trapped in solid neon at temperatures near 4 K. Molecules for which infrared spectra have been obtained and which will be discussed include NO_3, NNO2 anion, BF3 cation, and O4 cation.

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