Solid-solute phase equilibria in aqueous solution: II. A potentiometric study of the aragonite-calcite transition

Details Solid-solute phase equilibria in aqueous solution: II. A potentiometric study of the aragonite-calcite transition Solid-solute phase equilibria in aqueous solution: II. A potentiometric study of the aragonite-calcite transition

Nov 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989gecoa..53.2807k&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 53, Issue 11, pp.2807-2810

Physics

3

Scientific paper

The free enthalpy change, calc arag G * T , and the entropy change, calc arag S * 298 , of the aragonite-calcite phase transition have been studied by an electrochemical method. A definitive set of thermodynamic data for the reaction CaCO 3(arag) CaCO 3(calc) is now available, and the results are consistent with those from direct determinations of the respective phase boundary.

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