Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential

Details Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential Simple Evaluation of Franck-Condon Factors and Non-Condon Effects in the Morse Potential

2001-09-06

arxiv.org/abs/physics/0109017v1

Physics

Chemical Physics

LaTeX, 27 pages, 7 Tables, 1 figure

Scientific paper

The calculation of Franck-Condon factors between different one-dimensional Morse potential eigenstates using a formula derived from the Wigner function is discussed. Our numerical calculations using a very simple program written in Mathematica is compared with other calculations. We show that our results have a similar accuracy as the calculations performed with more sophisticated methods. We discuss the extension of our method to include non-Condon effects in the calculation.

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